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摘(zhai)要:本文對(dui)輕質碳酸(suan)鈣的填充(chong)機制及其影(ying)響(xiang)因素進行了(le)分析。了(le)解輕質碳酸(suan)鈣的填充(chong)機制以及影(ying)響(xiang)因素對(dui)于優(you)化橡(xiang)膠填充(chong)技術和提高橡(xiang)膠制品的性(xing)能(neng)具有重要意義。
正(zheng)文(wen):橡(xiang)(xiang)膠填(tian)(tian)充(chong)是一種(zhong)常(chang)用的(de)橡(xiang)(xiang)膠制品(pin)生產技(ji)術,通過(guo)將填(tian)(tian)充(chong)劑(ji)加入橡(xiang)(xiang)膠基(ji)質(zhi)中(zhong),可(ke)以改(gai)變橡(xiang)(xiang)膠的(de)性能和特性。輕質(zhi)碳酸鈣(gai)作(zuo)為一種(zhong)常(chang)用的(de)橡(xiang)(xiang)膠填(tian)(tian)充(chong)劑(ji),其填(tian)(tian)充(chong)機制受多種(zhong)因(yin)素(su)的(de)影(ying)響。
首先(xian),輕(qing)(qing)質(zhi)碳(tan)酸鈣(gai)的填(tian)充機(ji)制主(zhu)要包括(kuo)機(ji)械(xie)填(tian)充和(he)(he)物理(li)(li)填(tian)充兩(liang)個方面。在機(ji)械(xie)填(tian)充過(guo)程(cheng)中,輕(qing)(qing)質(zhi)碳(tan)酸鈣(gai)的顆(ke)粒與橡(xiang)膠(jiao)基質(zhi)的分子間(jian)隙(xi)相互填(tian)充,填(tian)充劑(ji)顆(ke)粒之(zhi)間(jian)的不(bu)規則形(xing)狀可以形(xing)成(cheng)網絡(luo)結構(gou),提高(gao)橡(xiang)膠(jiao)的強度(du)和(he)(he)硬度(du)。在物理(li)(li)填(tian)充過(guo)程(cheng)中,輕(qing)(qing)質(zhi)碳(tan)酸鈣(gai)的顆(ke)粒與橡(xiang)膠(jiao)分子之(zhi)間(jian)的分散相互作用形(xing)成(cheng)物理(li)(li)紐帶,提高(gao)橡(xiang)膠(jiao)的柔韌性(xing)和(he)(he)延展性(xing)。
其(qi)次,影(ying)響(xiang)輕質碳酸鈣(gai)填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)效(xiao)(xiao)果(guo)(guo)的(de)(de)(de)因(yin)素(su)(su)包括填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)與(yu)基(ji)(ji)質的(de)(de)(de)相互作用、填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)性質和填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)含(han)量。填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)與(yu)基(ji)(ji)質的(de)(de)(de)相互作用是影(ying)響(xiang)填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)效(xiao)(xiao)果(guo)(guo)的(de)(de)(de)關鍵因(yin)素(su)(su)之一(yi)。當填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)與(yu)基(ji)(ji)質之間具有較好(hao)的(de)(de)(de)相容性時,填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)能夠更(geng)好(hao)地與(yu)基(ji)(ji)質結合,提高(gao)填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)效(xiao)(xiao)果(guo)(guo)。填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)性質也會(hui)影(ying)響(xiang)填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)效(xiao)(xiao)果(guo)(guo),如填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)的(de)(de)(de)表面活性、粒度分布和顆粒形態等。填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)含(han)量是另一(yi)個(ge)重(zhong)要的(de)(de)(de)影(ying)響(xiang)因(yin)素(su)(su),填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)劑(ji)(ji)(ji)含(han)量過高(gao)或過低都可(ke)能導(dao)致(zhi)填(tian)(tian)(tian)(tian)充(chong)(chong)(chong)(chong)效(xiao)(xiao)果(guo)(guo)不理想。
此外(wai),填(tian)充(chong)劑(ji)的(de)(de)(de)分散性(xing)和(he)分布(bu)均勻性(xing)也會影響輕質碳酸(suan)鈣的(de)(de)(de)填(tian)充(chong)效(xiao)果。充(chong)分的(de)(de)(de)分散性(xing)能夠使填(tian)充(chong)劑(ji)與基質更好(hao)地(di)混合,提高填(tian)充(chong)效(xiao)果。而分布(bu)均勻性(xing)能夠保(bao)證填(tian)充(chong)劑(ji)在橡膠制品中的(de)(de)(de)均勻分布(bu),避免出現局(ju)部(bu)填(tian)充(chong)不足或過(guo)度填(tian)充(chong)引(yin)起(qi)的(de)(de)(de)問(wen)題。
綜(zong)上所(suo)述(shu),輕(qing)質碳酸鈣的(de)(de)填(tian)充(chong)(chong)機(ji)制主要包(bao)括機(ji)械填(tian)充(chong)(chong)和物理填(tian)充(chong)(chong)。影響輕(qing)質碳酸鈣填(tian)充(chong)(chong)效果的(de)(de)因素(su)包(bao)括填(tian)充(chong)(chong)劑(ji)(ji)與(yu)基質的(de)(de)相互作用、填(tian)充(chong)(chong)劑(ji)(ji)性(xing)質、填(tian)充(chong)(chong)劑(ji)(ji)含量以及填(tian)充(chong)(chong)劑(ji)(ji)的(de)(de)分散性(xing)和分布均勻性(xing)。了解這(zhe)些影響因素(su)對于優(you)化橡膠(jiao)填(tian)充(chong)(chong)技(ji)術(shu)和提高橡膠(jiao)制品的(de)(de)性(xing)能具有重要意義。